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Chem Commun (Camb). 2013 Oct 14;49(80):9140-2. doi: 10.1039/c3cc45308a. Epub 2013 Aug 28.

Improvement of hydrothermal stability of zeolitic imidazolate frameworks.

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1
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, CAS, Zhongshan Road 457, 116023, Dalian, China. leeys@dicp.ac.cn yangws@dicp.ac.cn.

Abstract

The metal-organic framework ZIF-8, which undergoes hydrolysis under hydrothermal conditions, is endowed with high water-resistance after a shell-ligand-exchange-reaction. The stabilized ZIF-8 retains its structural characteristics with improved application performances in adsorption and membrane separation.

PMID:
23985705
DOI:
10.1039/c3cc45308a
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