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Dalton Trans. 2013 Oct 21;42(39):14045-8. doi: 10.1039/c3dt52086b.

Octametallic 4f-phosphonate horseshoes.

Author information

1
School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester M13 9PL, UK. richard.winpenny@manchester.ac.uk.

Abstract

Three octanuclear phosphonate clusters, formulated as [Ln8(O3P(t)Bu)6(μ3-OH)2(H2O)2(HO(i)Bu)(O2C(t)Bu)12](NH3(i)Pr)2 (Ln = Gd, Dy and Tb), were synthesised by refluxing a mixture of pivalic acid (HO2C(t)Bu), Ln(NO3)3·6H2O, tert-Butyl phosphonic acid (H2O3P(t)Bu) and isopropylamine ((i)PrNH2) in isobutyl alcohol (i)BuOH.

PMID:
23970069
DOI:
10.1039/c3dt52086b

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