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Org Biomol Chem. 2013 Oct 7;11(37):6258-62. doi: 10.1039/c3ob41155a.

Modular synthesis of all-substituted furans through oxidative carbonylation of cyclopropenes with tandem metal relay catalysis.

Author information

1
Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, People's Republic of China.

Abstract

A modular synthesis of tetrasubstituted furan carboxylates using a tandem cycloisomerization/oxidative carbonylation sequence of cyclopropenes has been successfully developed. The Tandem Metal Relay Catalysis (TMRC) pathway accounted for the high efficiency of this transformation.

PMID:
23959259
DOI:
10.1039/c3ob41155a
[Indexed for MEDLINE]

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