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Chemistry. 2013 Sep 2;19(36):11874-7. doi: 10.1002/chem.201302700. Epub 2013 Aug 16.

Design and preparation of molybdenum-dinitrogen complexes with ferrocenyldiphosphine and pentamethylcyclopentadienyl moieties as auxiliary ligands.

Author information

1
School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656 (Japan), Fax: (+81) 3-5841-1175.

Abstract

Fix me! Molybdenum-dinitrogen complexes containing ferrocenyldiphosphine and pentamethylcyclopentadienyl moieties as auxiliary ligands have been designed, prepared, and characterized. The ferrocenyldiphosphine works as a unique ligand to inhibit dissociation of dinitrogen, as well as to make the coordinated molecular dinitrogen reactive toward electrophiles.

KEYWORDS:

dinitrogen complexes; iron; molybdenum; nitrogen fixation

PMID:
23956064
DOI:
10.1002/chem.201302700
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