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ACS Nano. 2013 Sep 24;7(9):7640-7. doi: 10.1021/nn4034986. Epub 2013 Aug 12.

Dynamic visualization of axial p-n junctions in single gallium nitride nanorods under electrical bias.

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1
Department of Physics, National Tsing-Hua University , Hsinchu 30013, Taiwan.

Abstract

We demonstrate a direct visualization method based on secondary electron (SE) imaging in scanning electron microscopy for mapping electrostatic potentials across axial semiconductor nanorod p-n junctions. It is found that the SE doping contrast can be directly related to the spatial distribution of electrostatic potential across the axial nanorod p-n junction. In contrast to the conventional SE doping contrast achieved for planar p-n junctions, the quasi-one-dimensional geometry of nanorods allows for high-resolution, versatile SE imaging under high accelerating voltage, long working distance conditions. Furthermore, we are able to delineate the electric field profiles across the axial nanorod p-n junction as well as depletion widths at different reverse biases. By using standard p-n junction theory and secondary ion mass spectroscopy, the carrier concentrations of p- and n-regions can be further extracted from the depletion widths under reverse biasing conditions. This direct imaging method enables determination of electrostatic potential variation of p-n junctions in semiconductor nanorod and nanowire devices with a spatial resolution better than 10 nm.

PMID:
23915124
DOI:
10.1021/nn4034986
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