Selective detection and bio-imaging of Pd2+ with novel 'C-CN' bond cleavage of cyano-rhodamine, cyanation with diaminomaleonitrile

Shyamaprosad Goswami; Abhishek Manna; Anup Kumar Maity; Sima Paul; Avijit Kumar Das; Manas Kumar Das; Partha Saha; Ching Kheng Quah; Hoong-Kun Fun

doi:10.1039/c3dt51591e

Selective detection and bio-imaging of Pd2+ with novel 'C-CN' bond cleavage of cyano-rhodamine, cyanation with diaminomaleonitrile

Dalton Trans. 2013 Sep 28;42(36):12844-8. doi: 10.1039/c3dt51591e. Epub 2013 Jul 30.

Authors

Shyamaprosad Goswami¹, Abhishek Manna, Anup Kumar Maity, Sima Paul, Avijit Kumar Das, Manas Kumar Das, Partha Saha, Ching Kheng Quah, Hoong-Kun Fun

Affiliation

¹ Department of Chemistry, Bengal Engineering and Science University, Shibpur, West Bengal, India. spgoswamical@yahoo.com.

PMID: 23900587
DOI: 10.1039/c3dt51591e

Abstract

A new rhodamine based chemosensor, cyano-rhodamine, has been designed and synthesized with a green approach which shows a specific 'C-CN' bond breaking with the action of the Pd(2+) ion to produce the specific color and fluorescence of rhodamine 6G itself in solution and in HeLa cells.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Cyanides / chemical synthesis
Cyanides / chemistry*
HeLa Cells
Humans
Models, Molecular
Palladium / analysis*
Rhodamines / chemical synthesis
Rhodamines / chemistry*
Spectrometry, Fluorescence

Substances

Cyanides
Rhodamines
Palladium