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Chemistry. 2013 Jul 22;19(30):9785-8. doi: 10.1002/chem.201300633. Epub 2013 Jun 12.

Nickel-catalysed hydroalkoxylation reaction of 1,3-butadiene: ligand controlled selectivity for the efficient and atom-economical synthesis of alkylbutenyl ethers.

Author information

1
UCCS (Unité de Catalyse et de Chimie du Solide), Université Lille Nord de France-ENSCL, BP 90108, 59652 Villeneuve d'Ascq, France.

Abstract

The nickel-catalysed hydroalkoxylation of butadiene is promoted by a nickel(0)/dppb catalyst (dppb = 1,4-bis(diphenylphosphino)butane; see scheme). By following this new synthetic procedure, alkylbutenyl ethers are readily obtained from an alcohol and 1,3-butadiene with exclusion of dimerisation and telomerisation products.

KEYWORDS:

butadiene; ethers; homogeneous catalysis; hydroalkoxylation; nickel

PMID:
23852957
DOI:
10.1002/chem.201300633

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