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Chem Commun (Camb). 2013 Aug 21;49(65):7258-60. doi: 10.1039/c3cc43278e. Epub 2013 Jul 11.

Planar tris-N-heterocyclic carbenes.

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1
Department of Chemistry, National Taiwan University, No. 1, Sec. 4, Roosevelt Rd., Taipei, Taiwan 10617.

Abstract

To further explore the coordination chemistry of poly-carbene complexes, two triphenylene-based planar tridentate N-heterocyclic carbenes and their corresponding tri-gold complexes were synthesized. Molecular structures of the tert-butyl substituted tritopic free carbene and the tri-nuclear gold complex were determined experimentally. A silver-dicarbene organometallic polymer was also prepared with the newly synthesized tris-NHC.

PMID:
23846191
DOI:
10.1039/c3cc43278e
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