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Org Biomol Chem. 2013 Aug 21;11(31):5057-64. doi: 10.1039/c3ob40828k. Epub 2013 Jul 2.

C-H···O non-classical hydrogen bonding in the stereomechanics of organic transformations: theory and recognition.

Author information

1
153 Gilbert Hall, Department of Chemistry, Oregon State University, Corvallis, OR, USA.

Abstract

This manuscript describes the role of non-classical hydrogen bonds (NCHBs), specifically C-HO interactions, in modern synthetic organic transformations. Our goal is to point out the seminal examples where C-H···O interactions have been invoked as a key stereocontrolling element and to provide predictive value in recognizing future and/or potential C-H···O interactions in modern transformations.

PMID:
23824256
DOI:
10.1039/c3ob40828k
[Indexed for MEDLINE]

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