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J Am Chem Soc. 2013 Jun 26;135(25):9322-5. doi: 10.1021/ja404526x. Epub 2013 Jun 17.

Pd(II)-catalyzed phosphorylation of aryl C-H bonds.

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1
Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, United States.

Abstract

A Pd(II)-catalyzed C-H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine oxides are suitable coupling partners for this reaction.

PMID:
23755825
DOI:
10.1021/ja404526x
[Indexed for MEDLINE]
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