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Acta Crystallogr C. 2013 Jun;69(Pt 6):613-5. doi: 10.1107/S0108270113012547. Epub 2013 May 17.

Di-μ2-chlorido-dichloridobis(dimethylformamide)tetrakis[μ3-1-(2-oxidobenzoyl)-2-(2-oxo-2-phenylethanethioyl)hydrazine-1,2-diido]octacopper(II) dimethylformamide disolvate.

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1
College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, People's Republic of China.

Abstract

The title compound, [Cu8(C15H10N3O3S)4Cl4(C3H7NO)2]·2C3H7NO, consisting of eight Cu(II) cations, four trianionic 1-(2-oxidobenzoyl)-2-(2-oxo-2-phenylethanethioyl)hydrazine-1,2-diide ligands, four chloride ligands and two coordinated and two solvent dimethylformamide molecules, crystallizes with the octanuclear molecule located on an inversion centre. The two halves of the molecule are connected by two bridging Cl atoms. This is the first example of an octanuclear complex based on a thiosemicarbazone-derived ligand.

PMID:
23744379
DOI:
10.1107/S0108270113012547
[Indexed for MEDLINE]
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