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Chem Commun (Camb). 2013 Aug 11;49(62):6968-70. doi: 10.1039/c3cc41811a.

Two novel innovanoside dimers from Daphne aurantiaca and a concise total synthesis of diinnovanoside A.

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1
Department of Natural Product Chemistry, School of Pharmacy, Second Military Medical University, Shanghai 200433, People's Republic of China.

Abstract

Chemical examination of the methanolic extract from the stem bark of Daphne aurantiaca led to the isolation of two innovanoside dimers (1 and 2) with an unusual four-membered cyclobutane ring, together with the isoinnovanoside 3. Their chemical structures and configurations were elucidated by extensive spectral analysis and synthesis.

PMID:
23687654
DOI:
10.1039/c3cc41811a
[Indexed for MEDLINE]
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