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Top Curr Chem. 2013;340:41-72. doi: 10.1007/128_2013_439.

Enantiomeric differentiation by synthetic helical polymers.

Author information

1
Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603, Japan, yashima@apchem.nagoya-u.ac.jp.

Abstract

Recent advances in the synthesis of helical polymers and their applications as chiral materials, in particular chiral stationary phases (CSPs), for high-performance liquid chromatography (HPLC) are reviewed with an emphasis on the key role of the helical conformations with one-handedness for the prominent chiral recognition of enantiomers. The historical background of artificial optically active helical polymers is also briefly described.

PMID:
23666081
DOI:
10.1007/128_2013_439
[Indexed for MEDLINE]
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