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Chem Commun (Camb). 2013 Jun 4;49(44):5043-5. doi: 10.1039/c3cc41552j. Epub 2013 Apr 26.

Total synthesis of (8R,6'R)-peridinin-5,8-furanoxide.

Author information

1
Department of Organic Chemistry As Lagoas-Marcosende, Universidade de Vigo, 36315 Vigo, Spain.

Abstract

The first total synthesis of (8R,6'R)-peridinin-5,8-furanoxide, a C37 xanthophyll norcarotenoid, has been achieved. The key steps of the synthetic sequence are a Julia-Kocienski condensation and a late stage stereoretentive Stille cross-coupling of an iodoallene.

PMID:
23619774
DOI:
10.1039/c3cc41552j
[Indexed for MEDLINE]

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