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Dalton Trans. 2013 Jun 14;42(22):7842-5. doi: 10.1039/c3dt50750e. Epub 2013 Apr 16.

Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size.

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  • 1Department of Bioinspired Science, Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea.

Abstract

The ring size effect of macrocyclic TMC ligands in nonheme iron(IV)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(IV)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe(IV/III) redox potential.

PMID:
23588673
DOI:
10.1039/c3dt50750e
[PubMed - indexed for MEDLINE]
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