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Chem Commun (Camb). 2013 May 21;49(41):4682-4. doi: 10.1039/c3cc41107a. Epub 2013 Apr 11.

Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group.

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1
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore.

Abstract

A highly efficient Pd-catalyzed ortho-alkenylation is reported using a mono-phosphoric acid-directing group for the first time. This phosphoric acid-directing group is successfully utilized for the synthesis of various alkenylated products and offers a new approach to transition-metal-catalyzed C-H activation.

PMID:
23579567
DOI:
10.1039/c3cc41107a
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