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Chem Commun (Camb). 2013 Apr 21;49(31):3200-2. doi: 10.1039/c3cc40635k. Epub 2013 Mar 14.

Chemically crosslinked isoreticular metal-organic frameworks.

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1
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093, USA.

Abstract

Herein we report the synthesis of canonical isoreticular metal-organic frameworks (IRMOFs) containing interligand crosslinks. Chemically crosslinking two molecules of 2-amino-1,4-benzene dicarboxylic acid (NH2-BDC) gives ligands that readily form IRMOF-1 analogs, producing crosslinked MOFs that may be designed to have novel properties.

PMID:
23486829
DOI:
10.1039/c3cc40635k
[Indexed for MEDLINE]
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