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Dalton Trans. 2013 Apr 28;42(16):5611-4. doi: 10.1039/c3dt50486g.

Enhancing the electronic coupling in a cyclometalated bisruthenium complex by using the 1,3,6,8-tetra(pyridin-2-yl)carbazole bridge.

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1
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

Abstract

A cyclometalated bisruthenium complex bridged by the 2,7-bisdeprotonated form of 1,3,6,8-tetra(pyridin-2-yl)-9-butyl-9H-carbazole displays appreciably enhanced electronic coupling relative to that with the 5,5'-bisdeprotonated form of 3,3',5,5'-tetra(pyridin-2-yl)-biphenyl as the bridge.

PMID:
23483123
DOI:
10.1039/c3dt50486g
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