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Chemistry. 2013 Apr 8;19(15):4664-78. doi: 10.1002/chem.201203707. Epub 2013 Feb 21.

Catalysis with N-heterocyclic carbenes under oxidative conditions.

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1
Institute of Organic Chemistry, Westfälische Wilhelms-University, Corrensstrasse 40, 48149 Münster, Germany.

Abstract

This Concept article discusses the potential of oxidative carbene catalysis in synthesis and comprehensively covers pioneering studies as well as recent developments. Oxidative carbene catalysis can be conducted by using inorganic and organic oxidants. Applications in cascade processes, in enantioselective catalysis, and also in natural product synthesis are discussed.

PMID:
23436489
DOI:
10.1002/chem.201203707

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