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Chem Commun (Camb). 2013 Mar 18;49(22):2231-3. doi: 10.1039/c3cc38655d.

An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission.

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1
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.

Abstract

The first example of an inorganic-organic composite framework with a 3D inorganic Cd-O-M (M = Cd, Rb) connectivity, featuring a unique {Cd(7)Rb}(n) helix and nanoscale {Cd(16)Rb(4)} and {Cd(18)Rb(2)} rings, has been constructed and structurally characterized. This compound exhibits white-light emission and a wavelength-dependent photochromic response.

PMID:
23396541
DOI:
10.1039/c3cc38655d
[Indexed for MEDLINE]
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