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J Am Chem Soc. 2013 Feb 6;135(5):1708-10. doi: 10.1021/ja3116197. Epub 2013 Jan 28.

Electrochemically mediated atom transfer radical polymerization on nonconducting substrates: controlled brush growth through catalyst diffusion.

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State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 China.


Surface initiated atom transfer radical polymerization (SI-ATRP) was triggered after diffusion of a Cu(I)/L activator generated at a working electrode. A stable [Cu(II)L]/[Cu(I)L] ratio gradient was formed at the gap between the working electrode and the initiator terminated substrate due to ion diffusion. The size of the gap can be used to dictate polymer growth kinetics at different gap distances. Gradient polymer brushes were grafted when substrate was placed at a tilting angle along [Cu(II)L]/[Cu(I)L] gradient.


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