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Chem Commun (Camb). 2013 Mar 18;49(22):2186-8. doi: 10.1039/c2cc38758a.

Chirality transcription and amplification by [2]pseudorotaxanes.

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1
Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan.

Abstract

Chirality transcription and amplification by the formation of chiral [2]pseudorotaxanes by an achiral crown ether having the 2',2''-quaterphenyl group and chiral sec-ammonium ions are reported. It was revealed that the absolute configurations of the chiral sec-ammonium ions can be detected directly from the CD spectra of the chiral [2]pseudorotaxanes.

PMID:
23318978
DOI:
10.1039/c2cc38758a
[Indexed for MEDLINE]
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