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J Am Chem Soc. 2012 Dec 19;134(50):20282-5. doi: 10.1021/ja3101165. Epub 2012 Dec 11.

Simultaneous determination of both the enantiomeric composition and concentration of a chiral substrate with one fluorescent sensor.

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1
Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States.

Abstract

A fluorescent sensor is discovered to exhibit high sensitivity at one emission wavelength and high enantioselectivity at another when treated with a chiral diamine. By using this fluorescent sensor, it is demonstrated for the first time that both the concentration and enantiomeric composition of a chiral substrate can be determined simultaneously with one fluorescence measurement.

PMID:
23214478
DOI:
10.1021/ja3101165

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