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Chem Commun (Camb). 2012 Dec 18;48(97):11892-4. doi: 10.1039/c2cc36083g.

Enhancement of the visible light absorption intensity of microporous vanadosilicate AM-6.

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1
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, China.

Abstract

AM-6 with high intensity visible light absorption at 400-800 nm was synthesized via a hydrothermal route in the presence of F(-) ions. Structure characterization and DFT calculations indicate that the unusual optical properties originate from the connection of octahedral VO(6) wires with distorted tetrahedral VO(4) units, which are stabilized in the framework of AM-6.

PMID:
23125974
DOI:
10.1039/c2cc36083g
[Indexed for MEDLINE]
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