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Chem Commun (Camb). 2012 Dec 11;48(95):11626-8. doi: 10.1039/c2cc37427g.

Transamidation of primary amides with amines catalyzed by zirconocene dichloride.

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1
University of Bath, UK.

Abstract

Zirconocene dichloride (Cp(2)ZrCl(2)) has been shown to be an effective catalyst for the transamidation of primary amides with amines in cyclohexane at 80 °C in 5-24 hours. For favourable substrates, the reaction can be performed at temperatures as low as 30 °C.

PMID:
23097018
DOI:
10.1039/c2cc37427g
[Indexed for MEDLINE]
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