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Org Biomol Chem. 2013 Jan 14;11(2):271-8. doi: 10.1039/c2ob26778k. Epub 2012 Oct 18.

Stereoselective synthesis of cyclic amino acids via asymmetric phase-transfer catalytic alkylation.

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1
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.

Abstract

An asymmetric synthesis of cyclic amino acids having piperidine and azepane core structures was realized starting from readily available glycine and alanine esters by combination of phase-transfer catalyzed asymmetric alkylation and subsequent reductive amination.

PMID:
23076259
DOI:
10.1039/c2ob26778k
[Indexed for MEDLINE]
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