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J Am Chem Soc. 2012 Oct 24;134(42):17456-8. doi: 10.1021/ja3084797. Epub 2012 Oct 12.

Nickel-mediated oxidative fluorination for PET with aqueous [18F] fluoride.

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1
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.

Abstract

A one-step oxidative fluorination for carbon-fluorine bond formation from well-defined nickel complexes with oxidant and aqueous fluoride is presented, which enables a straightforward and practical (18)F late-stage fluorination of complex small molecules with potential for PET imaging.

PMID:
23061667
PMCID:
PMC3494465
DOI:
10.1021/ja3084797
[Indexed for MEDLINE]
Free PMC Article
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