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Chem Commun (Camb). 2012 Nov 11;48(87):10742-4. doi: 10.1039/c2cc32142d.

Synthesis of ethers from esters via Fe-catalyzed hydrosilylation.

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1
Leibniz-Insitut für Katalyse e.V., Albert-Einstein-Strasse 29a, 18059, Rostock, Germany.

Abstract

Triiron dodecacarbonyl allows for the selective reduction of esters into the corresponding ethers. This protocol has a wide substrate scope. In addition, cholesteryl pelarogonate has been reduced under the reaction conditions with an excellent yield.

PMID:
23024977
DOI:
10.1039/c2cc32142d
[Indexed for MEDLINE]
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