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Inorg Chem. 2012 Oct 15;51(20):11150-4. doi: 10.1021/ic3017479. Epub 2012 Sep 28.

The first uranyl arsonates featuring heterometallic cation-cation interactions with U(VI)═O-Zn(II) bonding.

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1
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China.

Abstract

Two new uranyl arsonates, Zn(UO(2))(PhAsO(3))(2)L·H(2)O [L = 1,10-phenanthroline (1) and 2,2'-bipyridine (2)], have been synthesized by hydrothermal reactions of phenylarsonic acid, L, and ZnUO(2)(OAc)(4)·7H(2)O. Single-crystal X-ray analyses demonstrate that these two compounds are isostructural and exhibit one-dimensional chains in which U(VI) and Zn(II) cations are directly connected by the yl oxygen atoms and additionally bridged by arsonate groups. Both compounds represent the first examples of uranyl arsonates with heterometallic cation-cation interactions.

PMID:
23020138
DOI:
10.1021/ic3017479
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