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Chem Commun (Camb). 2012 Nov 7;48(86):10651-3. doi: 10.1039/c2cc35078e.

Crystal surface mediated structure transformation of a kinetic framework composed of multi-interactive ligand TPHAP and Co(II).

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1
The Division of Advanced Materials Science, Pohang University of Science and Technology, (POSTECH), San-31, Hyoja-dong, Namgu, Pohang 790-784, South Korea.

Abstract

A tripyridyl multi-interactive ligand TPHAP is prepared by a one-pot reaction on a gram scale. Network formation of Co(ii) with TPHAP(-) gave kinetic and thermally more stable products. The kinetic network showed an unprecedented dynamic network transformation on the crystal surface by a ligand exchange reaction.

PMID:
23000952
DOI:
10.1039/c2cc35078e
[Indexed for MEDLINE]
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