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Chem Commun (Camb). 2012 Oct 21;48(82):10237-9.

Tuning the breathing behaviour of MIL-53 by cation mixing.

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1
Institut Lavoisier, UMR 8180 CNRS - Université de Versailles St-Quentin en Yvelines, 45 av. des Etats-Unis, 78035 Versailles, France.

Abstract

A mixed cation MIL-53(Cr-Fe) MOF has been obtained by direct synthesis. Multiple experimental techniques have demonstrated the presence of a genuine mixed phase, leading to a breathing behaviour different from either of the single cation analogues.

PMID:
22968060
DOI:
10.1039/c2cc35348b
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