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Dalton Trans. 2012 Oct 21;41(39):11989-91.

Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker.

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1
Centre for Applied Chemical Research, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710054, China. zheng.yanzhen@mail.xjtu.edu.cn

Abstract

A two-dimensional coordination network, (2)(∞)[Fe(III) (OH)(e,a-cis-1,4-chdc)] (1,4-chdc: cyclohexane-1,4-dicarboxylate), featuring one-dimensional iron(III)-hydroxy chains that are transversely bridged by 1,4-chdc in its pure e,a-cis conformation have been isolated. The magnetic study shows a typical spin-5/2 Heisenberg chain above 20 K, but canted antiferromagnetic ordering at lower temperatures.

PMID:
22945794
DOI:
10.1039/c2dt31613g
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