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Angew Chem Int Ed Engl. 2012 Sep 24;51(39):9838-41. doi: 10.1002/anie.201204073. Epub 2012 Aug 31.

Synthesis and characterization of a metallapyridyne complex.

Author information

1
Department of Chemistry, College of Chemistry and Chemical Engineering, and State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, China.

Abstract

Building bridges: The first m-metallapyridine and the first metallapyridyne were synthesized under mild reaction conditions. The two complexes are metal-bridged polycyclic metallabenzenoid aromatics, in which the transition-metal center is shared by both six-membered rings. The synthetic method permits the use of metallabenzene as a starting material to access higher π-electron metallaaromatics.

PMID:
22936466
DOI:
10.1002/anie.201204073

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