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Angew Chem Int Ed Engl. 2012 Sep 24;51(39):9780-3. doi: 10.1002/anie.201204913. Epub 2012 Aug 21.

Magnesium borohydride: from hydrogen storage to magnesium battery.

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Materials Research Department, Toyota Research Institute of North America, Ann Arbor, MI 48105, USA.


Beyond hydrogen storage: The first example of reversible magnesium deposition/stripping onto/from an inorganic salt was seen for a magnesium borohydride electrolyte. High coulombic efficiency of up to 94 % was achieved in dimethoxyethane solvent. This Mg(BH(4))(2) electrolyte was utilized in a rechargeable magnesium battery.

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