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Dalton Trans. 2012 Oct 14;41(38):11559-61. doi: 10.1039/c2dt31457f. Epub 2012 Aug 17.

A self-catenated network containing unprecedented 0D + 2D → 2D polycatenation array.

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1
College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou, Jiangxi, China.

Abstract

Herein, we report a new acylamide ligand and its application in the construction of a metal-organic framework. The resultant acylamide metal-organic framework, namely [Zn(2)(L)(OH)(btc)](n) (1, L = N(1),N(4)-bis(pyridin-3-ylmethyl) naphthalene-1,4-dicarboxamide, H(3)btc = benzene-1,3,5-tricarboxylic acid), was obtained by hydrothermal synthesis. The outstanding structural feature of it is the 0D + 2D → 2D polycatenation array containing a self-catenated feature which has never previously been observed. To the best of our knowledge, the coexistence of self-catenation and polycatenation phenomena is highly exceptional.

PMID:
22903056
DOI:
10.1039/c2dt31457f
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