Format

Send to

Choose Destination
Nat Mater. 2012 Sep;11(9):802-7. doi: 10.1038/nmat3385. Epub 2012 Aug 5.

A Janus cobalt-based catalytic material for electro-splitting of water.

Author information

1
Laboratoire de Chimie et Biologie des Métaux (CEA/Université Grenoble 1/CNRS), 17 rue des Martyrs, 38054 Grenoble cedex 09, France.

Abstract

The future of energy supply depends on innovative breakthroughs regarding the design of cheap, sustainable and efficient systems for the conversion and storage of renewable energy sources. The production of hydrogen through water splitting seems a promising and appealing solution. We found that a robust nanoparticulate electrocatalytic material, H(2)-CoCat, can be electrochemically prepared from cobalt salts in a phosphate buffer. This material consists of metallic cobalt coated with a cobalt-oxo/hydroxo-phosphate layer in contact with the electrolyte and mediates H(2) evolution from neutral aqueous buffer at modest overpotentials. Remarkably, it can be converted on anodic equilibration into the previously described amorphous cobalt oxide film (O(2)-CoCat or CoPi) catalysing O(2) evolution. The switch between the two catalytic forms is fully reversible and corresponds to a local interconversion between two morphologies and compositions at the surface of the electrode. After deposition, the noble-metal-free coating thus functions as a robust, bifunctional and switchable catalyst.

PMID:
22863815
DOI:
10.1038/nmat3385

Supplemental Content

Full text links

Icon for Nature Publishing Group
Loading ...
Support Center