Format

Send to

Choose Destination
Acta Crystallogr C. 2012 Aug;68(Pt 8):m219-22. doi: 10.1107/S0108270112030582. Epub 2012 Jul 19.

Poly[[(μ2-4,4'-bipyridine)(μ3-5-isonicotinamidoisophthalato)cobalt(II)] trihydrate].

Author information

1
Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, Hunan, People's Republic of China.

Abstract

In the title compound, {[Co(C(14)H(8)N(2)O(5))(C(10)H(8)N(2))]·3H(2)O}(n), the Co(II) cation is five-coordinated with a slightly distorted trigonal-bipyramidal geometry, and the 5-isonicotinamidoisophthalate ligands link Co(II) atoms into a layered structure. These two-dimensional arrays are further pillared by rod-like 4,4'-bipyridine ligands to give a three-dimensional framework with pcu (primitive cubic) topology. The magnetic and adsorption properties of the title compound are also discussed.

PMID:
22850846
DOI:
10.1107/S0108270112030582

Supplemental Content

Loading ...
Support Center