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Inorg Chem. 2012 Jul 16;51(14):7439-41. doi: 10.1021/ic3007475. Epub 2012 Jun 28.

A μ9-iodide in a tricapped trigonal-prismatic geometry.

Author information

1
Department of Chemistry, National Dong Hwa University, Hualien, Taiwan 97401, Republic of China.

Abstract

Two luminescent, undecanuclear silver complexes [Ag(11)(μ(9)-I)(μ(3)-I)(3){E(2)P(O(i)Pr)(2)}(6)](PF(6)) [E = S (yellow), 1; Se (orange), 2], containing the first μ(9)-iodine inscribed at the center of a pentacapped trigonal-prismatic silver skeleton, were reported.

PMID:
22741566
DOI:
10.1021/ic3007475

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