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Angew Chem Int Ed Engl. 2012 Jul 27;51(31):7794-8. doi: 10.1002/anie.201202584. Epub 2012 Jun 18.

Chemoselective transfer hydrogenation to nitroarenes mediated by cubane-type Mo3S4 cluster catalysts.

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1
Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, 12071 Castelló de la Plana, Spain.

Abstract

Chemoselective cubes: Cubane-type [Mo(3)S(4)X(3)(dmpe)(3)](+) clusters (dmpe = 1,2-(bis)dimethylphosphinoethane), in combination with an azeotropic 5:2 mixture of HCOOH and NEt(3) as the reducing agent, act as selective cluster catalysts (X = H) or precatalysts (X = Cl) for the transfer hydrogenation of functionalized nitroarenes, without the formation of hazardous hydroxylamines.

PMID:
22711684
DOI:
10.1002/anie.201202584
[Indexed for MEDLINE]
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