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Angew Chem Int Ed Engl. 2012 Jul 27;51(31):7786-9. doi: 10.1002/anie.201202455. Epub 2012 Jun 18.

Asymmetric synthesis and biosynthetic implications of (+)-fusarisetin A.

Author information

1
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663N Zhongshan Road, Shanghai 200062, China.

Abstract

Starting from equisetin, the asymmetric synthesis of (+)-fusarisetin A has been accomplished in a one-pot transformation including a biomimetic oxidation and an intramolecular Diels-Alder/Roskamp reaction. Peroxyfusarisetin is proposed as a plausible biosynthetic intermediate based on studies of the oxidation of equisetin.

PMID:
22711675
DOI:
10.1002/anie.201202455
[Indexed for MEDLINE]

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