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Nano Lett. 2012 Jul 11;12(7):3574-80. doi: 10.1021/nl301207e. Epub 2012 Jun 13.

Strong and stable doping of carbon nanotubes and graphene by MoOx for transparent electrodes.

Author information

1
Stanford University, Stanford, California 94305, United States.

Abstract

MoO(x) has been used for organic semiconductor doping, but it had been considered an inefficient and/or unstable dopant. We report that MoO(x) can strongly and stably dope carbon nanotubes and graphene. Thermally annealed MoO(x)-CNT composites can form durable thin film electrodes with sheet resistances of 100 Ω/sq at 85% transmittance plain and 85 Ω/sq at 83% transmittance with a PEDOT:PSS adlayer. Sheet resistances change less than 10% over 20 days in ambient and less than 2% with overnight heating to 300 °C in air. The MoO(x) can be easily deposited either by thermal evaporation or from solution-based precursors. Excellent stability coupled with high conductivity makes MoO(x)-CNT composites extremely attractive candidates for practical transparent electrodes.

PMID:
22694046
DOI:
10.1021/nl301207e

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