Format

Send to

Choose Destination
J Am Chem Soc. 2012 Jun 20;134(24):9864-7. doi: 10.1021/ja302668n. Epub 2012 Jun 12.

Two pathways for the formation of ethylene in CO reduction on single-crystal copper electrodes.

Author information

1
Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, P.O. Box 9502, 2300 RA Leiden, The Netherlands.

Abstract

Carbon monoxide is a key intermediate in the electrochemical reduction of carbon dioxide to methane and ethylene on copper electrodes. We investigated the electrochemical reduction of CO on two single-crystal copper electrodes and observed two different reaction mechanisms for ethylene formation: one pathway has a common intermediate with the formation of methane and takes place preferentially at (111) facets or steps, and the other pathway involves selective reduction of CO to ethylene at relatively low overpotentials at (100) facets. The (100) facets seem to be the dominant crystal facets in polycrystalline copper, opening up new routes to affordable (photo)electrochemical production of hydrocarbons from CO(2).

PMID:
22670713
DOI:
10.1021/ja302668n

Supplemental Content

Full text links

Icon for American Chemical Society
Loading ...
Support Center