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Chem Commun (Camb). 2012 Jun 11;48(46):5793-5. doi: 10.1039/c2cc31148h. Epub 2012 Apr 12.

Enantioselective bromolactonization of cis-1,2-disubstituted olefinic acids using an amino-thiocarbamate catalyst.

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1
Department of Chemistry, NUS, 3 Science Drive 3, Singapore, 11754, Singapore.

Abstract

A facile, highly regio- and enantioselective amino-thiocarbamate-catalyzed bromolactonization of cis-1,2-disubstituted olefinic acids has been developed. The use of the enantio-enriched lactones in the synthesis of chiral synthetic intermediates is also demonstrated.

PMID:
22499150
DOI:
10.1039/c2cc31148h
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