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Inorg Chem. 2012 May 7;51(9):4925-30. doi: 10.1021/ic201629a. Epub 2012 Apr 9.

From lithium bis(trimethylsilyl)amide with cyanoamine into triazine compounds: synthesis and structures of lithium 6-((trimethylsilyl)amido)-2,4-bis(dimethylamino)[1,3,5]triazines and their manganese and cobalt complexes.

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1
Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People's Republic of China. mszhou@sxu.edu.cn

Abstract

Addition reactions of lithium bis(trimethylsilyl)amide with dimethylcyanamide lead to novel lithium salts of 6-((trimethylsilyl)amido)-2,4-bis(dimethylamino)[1,3,5]triazines [LLi(D)](2) (L = NC(NMe(2))NC(NMe(2))NC(NSiMe(3)); D = Me(2)NCN (1), Et(2)O (2)) and to the Mn and Co complexes [LL'M] (L' = N{N(SiMe(3))C(NMe(2))}(2); M = Mn (3), Co (4)); the structures of crystalline 1, 3, and 4 are reported. Their formation involves trimethylsilyl shifts, ring formation, and unusual Me(2)NSiMe(3) elimination.

PMID:
22486357
DOI:
10.1021/ic201629a
[Indexed for MEDLINE]
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