Format

Send to

Choose Destination
See comment in PubMed Commons below
Mar Pollut Bull. 2012 May;64(5):919-25. doi: 10.1016/j.marpolbul.2012.03.008. Epub 2012 Apr 2.

Hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBPA) in riverine and estuarine sediments of the Pearl River Delta in southern China, with emphasis on spatial variability in diastereoisomer- and enantiomer-specific distribution of HBCD.

Author information

1
State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China.

Abstract

Hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBPA) were measured in surface sediments in the Pearl River Delta, southern China. The concentrations ranged from 0.06 to 304 ng/g dry weight for TBBPA and from 0.03 to 31.6 ng/g for total HBCD. The correlations between the TBBPA and HBCD concentrations were significant in rivers (Dongjiang, Zhujiang, Beijiang, and Dayanhe Rivers) with local input sources but not significant in the Xijiang River and Pearl River Estuary without local sources. HBCD was dominated by γ-HBCD (averaged 52.5-75.0%), whereas α-HBCD contributions were relatively high in sediments from the urban areas. The enantiomeric fractions of γ-HBCD in the sediments (averaged from 0.431 ± 0.035 to 0.479 ± 0.010) differed significantly from that in HBCD technical product except for samples from the e-waste area (Dayanhe River, 0.488 ± 0.091). This suggests that enantioselective biotransformation of HBCD occurs in the aquatic environment in this region.

PMID:
22475420
DOI:
10.1016/j.marpolbul.2012.03.008
[Indexed for MEDLINE]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for Elsevier Science
    Loading ...
    Support Center