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Chem Commun (Camb). 2012 May 4;48(35):4220-2. doi: 10.1039/c2cc30326d. Epub 2012 Mar 22.

PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response.

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1
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, P. R. China.

Abstract

A new polar material containing two types of stereoactive lone-pairs has been synthesized. The unique parallel alignment of the stereoactive lone-pairs on Pb(2+) cations and the synergistic effect of two types of stereoactive lone-pairs on I(5+) and Pb(2+) cations make it exhibit a very large second-harmonic generation response of about 8 × KDP (KH(2)PO(4)).

PMID:
22441625
DOI:
10.1039/c2cc30326d
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