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Chem Commun (Camb). 2012 Apr 28;48(34):4046-8. doi: 10.1039/c2cc30366c. Epub 2012 Mar 20.

Induction of chirality in porphyrin-(bis)calixarene assemblies: a mixed covalent-non-covalent vs a fully non-covalent approach.

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1
Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania, Italy.

Abstract

CD and UV-vis measurements were carried out to demonstrate chirality induction-promoted by chiral covalently linked groups and non-covalently bound Δ- and Λ-[Ru(phen)(3)](2+) enantiomers-in metallo-porphyrin-calixarene and metallo-porphyrin-bis-calixarene non-covalent assemblies, respectively.

PMID:
22430063
DOI:
10.1039/c2cc30366c
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