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Org Lett. 2012 Apr 6;14(7):1846-9. doi: 10.1021/ol300450j. Epub 2012 Mar 19.

Synthesis of a wide range of thioethers by indium triiodide catalyzed direct coupling between alkyl acetates and thiosilanes.

Author information

1
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

Abstract

An indium triiodide-catalyzed substitution of the acetoxy group in alkyl acetates with thiosilanes provides access to a variety of thioethers. The method is efficient for a wide scope of acetates such as primary alkyl, secondary alkyl, tertiary alkyl, allylic, benzylic, and propargylic acetates.

PMID:
22428542
DOI:
10.1021/ol300450j
[Indexed for MEDLINE]

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