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Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m246-7. doi: 10.1107/S160053681200390X. Epub 2012 Feb 4.

Dichlorido{1-[N-(5-chloro-2-oxidophen-yl)carboximido-yl]naphthalen-2-olato-κO,N,O'}(methanol-κO)tin(IV).

Abstract

In the title complex, [Sn(C(17)H(10)ClNO(2))Cl(2)(CH(3)OH)], the Sn(IV) atom features a distorted octa-hedral geometry defined by the O,N,O'-donors of the dianion, two Cl atoms and the methanol O atom. The six-membered chelate ring has a half-chair conformation with the Sn atom lying 0.449 (4) Å out of the plane defined by the remaining atoms (r.m.s. deviation = 0.0238 Å). Supra-molecular helical chains along [100], mediated by O-H⋯O hydrogen bonds, feature in the crystal packing. Chains are linked by C-H⋯O, C-H⋯Cl and π-π [centroid-centroid distance = 3.598 (2) Å] inter-actions.

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