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Org Lett. 2012 Apr 6;14(7):1736-9. doi: 10.1021/ol300325t. Epub 2012 Mar 12.

ipso-Nitration of arylboronic acids with bismuth nitrate and perdisulfate.

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1
Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400076, India.

Abstract

An efficient and one pot synthetic method of ipso-nitration of arylboronic acids has been developed. The high efficiency, general applicability, and broader substrate scope including heterocycles and functional groups make this method advantageous. Due to its simplicity, we expect to find application of this method in synthesis.

PMID:
22409632
DOI:
10.1021/ol300325t
[Indexed for MEDLINE]
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